Jianglong Zhu
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Professor
Associate Professor
Assistant Professor, Chemistry & Biochemistry , College of Natural Sciences and Mathematics
Contact Info
Publications
selected publications
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Article (Faculty180)
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2022Cationic gold(I)-catalyzed glycosylation with glycosyl -1,1-dimethylpropargyl carbamate donors. Organic & biomolecular chemistry. 20:7006-7010.
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2022Cationic gold(I)-catalyzed glycosylation with glycosyl S-3-butynyl thiocarbonate donors. Journal of Carbohydrate Chemistry. 41:223-237.
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2022Stereoselective Synthesis of β-d-Manno-heptopyranoside via CsCO-Mediated Anomeric -Alkylation: Synthesis of a Tetrasaccharide Repeat Unit of Surface-Layer Glycoprotein. The Journal of organic chemistry. 87:6588-6600.
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2021Recent advances in direct synthesis of 2-deoxy glycosides and thioglycosides. Tetrahedron. 88:132140.
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2021Stereoselective β-Mannosylation via Anomeric -Alkylation with L-Sugar-Derived Electrophiles. European journal of organic chemistry. 2021:6682-6687.
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2020A New Era of Discovery in Carbohydrate Chemistry. Journal of Organic Chemistry. 85:15770-15772.
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2020
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2020β-Mannosylation via O-Alkylation of Anomeric Cesium Alkoxides: Mechanistic Studies and Synthesis of the Hexasaccharide Core of Complex Fucosylated N-Linked Glycans. European Journal of Organic Chemistry. 2291-2301.
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2019Facile synthesis of sugar lactols via bromine-mediated oxidation of thioglycosides. Journal of Carbohydrate Chemsitry. 38:109-126.
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2019Synthesis and antitumor activities of aquayamycin and analogues of derhodinosylurdamycin A. Organic and Biomolecular Chemistry. 17:2691-2704.
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2017Stereoselective β-Mannosylation via Anomeric O-Alkylation: Concise Synthesis of β-D-Xyl-(l→2)-β-D-Man-(1→4)-α-D-Glc-OMe, a Trisaccharide Oligomer of the Hyriopsis schlegelii Glycosphingolipid.. Journal of Carbohydrate Chemistry. 36:162-172.
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Article (Web of Science)
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2020Stereoselective Synthesis of 2-Azido-2-deoxy-beta-D-mannosides via Cs2CO3-Mediated Anomeric O-Alkylation with Primary Triflates: Synthesis of a Tetrasaccharide Fragment of Micrococcus luteus Teichuronic Acid. JOURNAL OF ORGANIC CHEMISTRY. 85:16196-16206.Full Text via DOI: 10.1021/acs.joc.0c02370 PMID: 33201716
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2020beta-Mannosylation through O-Alkylation of Anomeric Cesium Alkoxides: Mechanistic Studies and Synthesis of the Hexasaccharide Core of Complex Fucosylated N-Linked Glycans. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. 2020:2291-2301.Full Text via DOI: 10.1002/ejoc.202000313 PMID: 32431565
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2019Synthesis and antitumor activities of aquayamycin and analogues of derhodinosylurdamycin A. ORGANIC & BIOMOLECULAR CHEMISTRY. 17:2691-2704.Full Text via DOI: 10.1039/c9ob00121b
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2019Facile synthesis of sugar lactols via bromine-mediated oxidation of thioglycosides. JOURNAL OF CARBOHYDRATE CHEMISTRY. 38:109-126.Full Text via DOI: 10.1080/07328303.2019.1581889 PMID: 31396001
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2017Synthesis of S-linked trisaccharide glycal of derhodinosylurdamycin A: Discovery of alkyl thiocyanate as an efficient electrophile for stereoselective sulfenylation of 2-deoxy glycosyl lithium. CARBOHYDRATE RESEARCH. 448:103-109.Full Text via DOI: 10.1016/j.carres.2017.06.005
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2017Stereoselective -mannosylation via anomeric O-Alkylation: Concise synthesis of -D-Xyl-(l2)--D-Man-(14)--D-Glc-OMe, a trisaccharide oligomer of the hyriopsis schlegelii glycosphingolipid. JOURNAL OF CARBOHYDRATE CHEMISTRY. 36:162-172.Full Text via DOI: 10.1080/07328303.2017.1390579
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2016Synthesis of the 2-deoxy trisaccharide glycal of antitumor antibiotics landomycins A and E. CARBOHYDRATE RESEARCH. 430:54-58.Full Text via DOI: 10.1016/j.carres.2016.04.031
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2016Stereoselective Construction of -Mannopyranosides by Anomeric O-Alkylation: Synthesis of the Trisaccharide Core of N-linked Glycans. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. 55:4767-4771.Full Text via DOI: 10.1002/anie.201600488
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2015Total Synthesis of Antitumor Antibiotic Derhodinosylurdamycin A. CHEMISTRY-A EUROPEAN JOURNAL. 21:13553-13557.Full Text via DOI: 10.1002/chem.201502113
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2015Stereoselective Synthesis of S-Linked Hexasaccharide of Landomycin A via Umpolung S-Glycosylation. ORGANIC LETTERS. 17:4530-4533.Full Text via DOI: 10.1021/acs.orglett.5b02223
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2015Fluoroalcohol-mediated reductive iodonio-Claisen rearrangement: Synthesis of complex ortho-substituted-allyl iodoarenes. FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING. 9:359-368.Full Text via DOI: 10.1007/s11705-015-1530-6
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2015Selective deprotection of benzyl (Bn) ethers in the presence of para-methoxybenzyl (PMB) ethers. TETRAHEDRON LETTERS. 56:1420-1422.Full Text via DOI: 10.1016/j.tetlet.2015.01.105
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2014Direct Synthesis of 2-Deoxy-beta-Glycosides via Anomeric O-Alkylation with Secondary Electrophiles. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 136:3172-3175.Full Text via DOI: 10.1021/ja4116956
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2014Sterioselective Synthesis of S-Linked 2-Deoxy Sugars. SYNLETT. 25:308-312.Full Text via DOI: 10.1055/s-0033-1340309
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2014Stereoselective Synthesis of alpha-Digitoxosides and alpha-Boivinosides via Chelation-Controlled Anomeric O-Alkylation. JOURNAL OF CARBOHYDRATE CHEMISTRY. 33:438-451.Full Text via DOI: 10.1080/07328303.2014.931965
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2013Catalytic Stereoselective Synthesis of beta-Digitoxosides: Direct Synthesis of Digitoxin and C1 '-epi-Digitoxin. JOURNAL OF ORGANIC CHEMISTRY. 78:12469-12476.Full Text via DOI: 10.1021/jo4021419
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2013Reductive iodonio-Claisen rearrangement of iodothiophene diacetates with allylsilanes: formal synthesis of Plavix (R). TETRAHEDRON LETTERS. 54:5464-5466.Full Text via DOI: 10.1016/j.tetlet.2013.07.138
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2013Umpolung Reactivity in the Stereoselective Synthesis of S-Linked 2-Deoxyglycosides. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. 52:8012-8016.Full Text via DOI: 10.1002/anie.201301682
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2013Studies of S-But-3-ynyl and gem-Dimethyl S-But-3-ynyl Thioglycoside Donors in Gold-Catalyzed Glycosylations. JOURNAL OF CARBOHYDRATE CHEMISTRY. 32:336-359.Full Text via DOI: 10.1080/07328303.2013.831433
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2013Gold-Catalyzed Synthesis of 2-Deoxy Glycosides Using S-But-3-ynyl Thioglycoside Donors. ACS CATALYSIS. 3:57-60.Full Text via DOI: 10.1021/cs300670k
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2012Synthesis of Complex ortho-Allyliodoarenes by Employing the Reductive Iodonio-Claisen Rearrangement. CHEMISTRY-A EUROPEAN JOURNAL. 18:12232-12236.Full Text via DOI: 10.1002/chem.201202049
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2012Recent Advances in Transition Metal-Catalyzed O-Glycosylations. JOURNAL OF CARBOHYDRATE CHEMISTRY. 31:284-324.Full Text via DOI: 10.1080/07328303.2012.683910
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2011Encouraging Progress in the ω-Aspartylation of Complex Oligosaccharides as a General Route to β-N-Linked Glycopolypeptides. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 133:1597-1602.Full Text via DOI: 10.1021/ja110115a
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2011Synthesis of the Azaphilones (+)-Sclerotiorin and (+)-8-O-Methylsclerotiorinamine Utilizing (+)-Sparteine Surrogates in Copper-Mediated Oxidative Dearomatization. JOURNAL OF ORGANIC CHEMISTRY. 76:2577-2584.Full Text via DOI: 10.1021/jo102448n
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2010A program for ligation at threonine sites: application to the controlled total synthesis of glycopeptides. TETRAHEDRON. 66:2277-2283.Full Text via DOI: 10.1016/j.tet.2010.01.067
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2009Biologics through Chemistry: Total Synthesis of a Proposed Dual-Acting Vaccine Targeting Ovarian Cancer by Orchestration of Oligosaccharide and Polypeptide Domains. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 131:4151-4158.Full Text via DOI: 10.1021/ja810147j
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2009From Synthesis to Biologics: Preclinical Data on a Chemistry Derived Anticancer Vaccine. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 131:9298-9303.Full Text via DOI: 10.1021/ja901415s
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2009On the preparation of enantiomerically pure isonitriles from amino acid esters and peptides. TETRAHEDRON LETTERS. 50:577-579.Full Text via DOI: 10.1016/j.tetlet.2008.11.069
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2009Preparation and reactions of N-thioformyl peptides from amino thioacids and isonitriles. TETRAHEDRON LETTERS. 50:2329-2333.Full Text via DOI: 10.1016/j.tetlet.2009.02.205
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2009Synthesis of Human Cancer Associated Globo-H (MBr1) Glycosylamino Acid: Some Mechanistic and Conformational Reinvestigations. HETEROCYCLES. 79:441.Full Text via DOI: 10.3987/com-08-s(d)82
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2009Synthesis of biotinylated tumor-associated carbohydrate antigens for immunological studies. TETRAHEDRON LETTERS. 50:712-714.Full Text via DOI: 10.1016/j.tetlet.2008.11.113
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2009Total Synthesis of the 2,6-Sialylated Immunoglobulin G Glycopeptide Fragment in Homogeneous Form. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 131:16669-16671.Full Text via DOI: 10.1021/ja907136d
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2008Enantioselective Synthesis of Bicyclo[2.2.2]octenones Using a Copper-Mediated Oxidative Dearomatization/[4 + 2] Dimerization Cascade. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 130:2738-2739.Full Text via DOI: 10.1021/ja711018z
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2008Native Chemical Ligation at Valine: A Contribution to Peptide and Glycopeptide Synthesis. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. 47:8521-8524.Full Text via DOI: 10.1002/anie.200803523
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2006Asymmetric Syntheses of (−)-Mitorubrin and Related Azaphilone Natural Products. ORGANIC LETTERS. 8:5169-5171.Full Text via DOI: 10.1021/ol062233m
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Book (Faculty180)
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20171,2-Bis(dimethylsilyl)benzene. Wiley.
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2017
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Conference Poster (Faculty180)
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Editorial Material (Web of Science)
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2020A New Era of Discovery in Carbohydrate Chemistry. JOURNAL OF ORGANIC CHEMISTRY. 15770-15772.Full Text via DOI: 10.1021/acs.joc.0c02548 PMID: 33334105
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Meeting Abstract (Web of Science)
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2018beta-Mannosylation via cesium carbonate-mediated anomeric O-alkylation: Mechanistic studies and synthetic applications. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.
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2014Direct and stereoselective synthesis of biologically significant 2-deoxy sugars. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.
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2014Stereoselective synthesis of S-linked 2-deoxy sugars for biological studies. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.
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2013Stereoselective synthesis of 2-deoxy beta-glycosides. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.
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2013Stereoselective synthesis of S- and C-linked alpha-glycosides. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.
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2013Studies towards the synthesis of urdamycin A aglycon. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.
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2012Gold-catalyzed stereoselective synthesis of 2-deoxy glycosides. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.
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2012Synthesis of ortho-allyliodoarenes employing reductive iodonio-claisen rearrangement. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.
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2012Umpolung reactivity in stereoselective synthesis of 2-deoxy glycosides. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.
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2012Umpolung reactivity in the stereoselective synthesis of 2-deoxy thioglycosides. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.
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Presentation (Faculty180)
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Review Article (Web of Science)
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2021Recent advances in direct synthesis of 2-deoxy glycosides and thioglycosides. TETRAHEDRON.Full Text via DOI: 10.1016/j.tet.2021.132140
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2016Glycosylation via Transition-Metal Catalysis: Challenges and Opportunities. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. 4724-4767.Full Text via DOI: 10.1002/ejoc.201600484
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2009Synthetic carbohydrate-based anticancer vaccines: the Memorial Sloan-Kettering experience. Expert Review of Vaccines. 1399-1413.Full Text via DOI: 10.1586/erv.09.95
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Contact
full name
- Jianglong Zhu
visualizations
Cumulative publications in Scholars@UToledo
