Stereoselective Synthesis of β-d-Manno-heptopyranoside via CsCO-Mediated Anomeric -Alkylation: Synthesis of a Tetrasaccharide Repeat Unit of Surface-Layer Glycoprotein Article (Faculty180)

cited authors

  • Meng, Shuai; Hettiarachchi, Ishani L; Bhetuwal, Bishwa R; Thapa, Prakash; Zhu, Jianglong

description

  • <p>Stereoselective synthesis of d-glycero- and l-glycero-β-d-mannoheptosides has been achieved by cesium carbonate-mediated β-selective anomeric -alkylation of the corresponding d-mannoheptoses. In addition, this method has been utilized in the total synthesis of a tetrasaccharide repeat unit of surface-layer glycoprotein.</p>

authors

publication date

  • 2022

published in

start page

  • 6588

end page

  • 6600

volume

  • 87