Stereoselective β-Mannosylation via Anomeric -Alkylation with L-Sugar-Derived Electrophiles Article (Faculty180)

cited authors

  • Hettiarachchi, Ishani L; Meng, Shuai; Chahine, Mira; Li, Xiaohua; Zhu, Jianglong

description

  • <p>A total synthesis of the trisaccharide repeat unit of serogroup E1 -antigen is reported. This synthesis features a key β-mannosylation reaction via cesium carbonate-mediated anomeric -alkylation of a partially protected D-mannose with an L-fucose-derived electrophile for the first time.</p>

authors

publication date

  • 2021

published in

start page

  • 6682

end page

  • 6687

volume

  • 2021