New silylated iminophosphorano(amino)phosphines Me3SiN=PPh2N(R)PPh2 (R = Et, Pr-n, Bu-n). Crystal and molecular structure of trimethylsilyliminophosphorano(propylamino)-diphenylphosphine Me3SiN=PPh2N(Pr-n)PPh2. Further oxidative derivatization with S, Se, and azides, titanium(IV) transmetalation of the imine, and syntheses of rhodium(I), palladium(II), and platinum(II) complexes of these iminophosphorano(amino)phosphines Article (Web of Science)
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