Mason, Mark R

Mark R Mason
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Professor, Chemistry & Biochemistry , College of Natural Sciences and Mathematics

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mark.mason5@utoledo.edu

https://www.markrmasonresearchgroup.com/

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selected publications

Article (Faculty180)
- 2023
  
  Bidentate and tridentate coordination modes of bis(3-methylindolyl)-2-(1-methylimidazolyl)methane in complexes of aluminum and gallium. Journal of Organometallic Chemistry. 984:122554.
- 2021
  
  New Class of Trianionic Constrained Geometry Ligands: Representative Complexes of Zirconium. Journal of Organometallic Chemistry. 944:121830.
- 2018
  
  Bidentate and Tridentate Coordination Modes of Bis(3-methylindolyl)-2-pyridylmethane in Complexes of Aluminum and Gallium: Structural Characterization of Bridging N-Indolide in a Dialuminum Complex. Journal of Organometallic Chemistry. 872:12-23.
- 2016
  
  Aluminum Alkoxide, Amide, and Halide Complexes Supported by a Bulky Dipyrromethene Ligand: Synthesis, Characterization, and Preliminary ε-Caprolactone Polymerization Activity. Dalton Transactions. 45:13787-13797.
Article (Web of Science)
- 2021
  
  New class of trianionic constrained geometry ligands: Representative complexes of zirconium. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 944.
  Full Text via DOI: 10.1016/j.jorganchem.2021.121830
- 2020
  
  Greening the curriculum at the University of Toledo School of green chemistry and engineering. PHYSICAL SCIENCES REVIEWS. 5.
  Full Text via DOI: 10.1515/psr-2020-0005
- 2018
  
  Bidentate and tridentate coordination modes of bis(3-methylindolyl)-2-pyridylmethane in complexes of aluminum and gallium: Structural characterization of bridging N-indolide in a dialuminum complex. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 872:12-23.
  Full Text via DOI: 10.1016/j.jorganchem.2018.07.024
- 2016
  
  Aluminum alkoxide, amide and halide complexes supported by a bulky dipyrromethene ligand: synthesis, characterization, and preliminary epsilon-caprolactone polymerization activity. DALTON TRANSACTIONS. 45:13787-13797.
  Full Text via DOI: 10.1039/c6dt02449a
- 2014
  
  Mono- and Bimetallic Aluminum Alkyl, Aryl, and Hydride Complexes of a Bulky Dipyrromethene Ligand. ORGANOMETALLICS. 33:4503-4511.
  Full Text via DOI: 10.1021/om500730g
- 2014
  
  Ion-Tagged Phosphines as Ligands for Suzuki Coupling of Aryl Halides in a Phosphonium Ionic Liquid. SYNLETT. 25:977-982.
  Full Text via DOI: 10.1055/s-0033-1340846
- 2012
  
  Synthesis and Calorimetric, Spectroscopic, and Structural Characterization of Isocyanide Complexes of Trialkylaluminum and Tri-tert-butylgallium. INORGANIC CHEMISTRY. 51:2494-2502.
  Full Text via DOI: 10.1021/ic202427z
- 2012
  
  Planar, Three-Coordinate Boron Monohydrides Ligated by Bis(3-methylindolyl)methanes. ORGANOMETALLICS. 31:191-196.
  Full Text via DOI: 10.1021/om2006694
- 2010
  
  Confirmation of Bridging N-Indolides in 3-Methylindole and Di- and Tri(3-methylindolyl)methane Complexes of Dimethyl-, Diethyl-, and Diisobutylaluminum. ORGANOMETALLICS. 29:5927-5935.
  Full Text via DOI: 10.1021/om100781k
- 2008
  
  Reaction of carbon monoxide with tri-tert-butylgallium: The first example of CO insertion into a gallium-carbon bond. INORGANICA CHIMICA ACTA. 361:3332-3337.
  Full Text via DOI: 10.1016/j.ica.2007.11.021
- 2005
  
  Deprotonated diindolylmethanes as dianionic analogues of scorpionate bis(pyrazolyl)borate ligands: synthesis and structural characterization of representative titanocene and zirconocene complexes. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 690:157-162.
  Full Text via DOI: 10.1016/j.jorganchem.2004.09.003
- 2005
  
  Analysis of the Hydroformylation Reaction over an Immobilized Catalyst in Supercritical Carbon Dioxide. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH. 44:4973-4981.
  Full Text via DOI: 10.1021/ie049125t
- 2005
  
  Fortuitous formation of [(LiCl)6{(Me2NCH2C8H5N)3P}2]: an amine-ligated hexameric lithium chloride aggregate. INORGANIC CHEMISTRY COMMUNICATIONS. 8:331-334.
  Full Text via DOI: 10.1016/j.inoche.2005.01.019
- 2004
  
  Remarkable Room-Temperature Insertion of Carbon Monoxide into an Aluminum−Carbon Bond of Tri-tert-butylaluminum. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 126:11812-11813.
  Full Text via DOI: 10.1021/ja046411n
- 2003
  
  Hydroformylation of 1-Hexene in Supercritical Carbon Dioxide: Characterization, Activity, and Regioselectivity Studies. ENVIRONMENTAL SCIENCE & TECHNOLOGY. 37:5424-5431.
  Full Text via DOI: 10.1021/es034544n
- 2003
  
  Hydroformylation of 1-hexene in supercritical carbon dioxide using a heterogeneous rhodium catalyst. 1. Effect of process parameters. The Journal of Supercritical Fluids. 25:183-196.
  Full Text via DOI: 10.1016/s0896-8446(02)00096-7
- 2003
  
  Supported platinum/tin complexes as catalysts for hydroformylation of 1-hexene in supercritical carbon dioxide. Catalysis Communications. 4:309-314.
  Full Text via DOI: 10.1016/s1566-7367(03)00058-x
- 2003
  
  Titanium and Zirconium Amido Complexes Ligated by 2,2‘-Di(3-methylindolyl)methanes: Synthesis, Characterization, and Ethylene Polymerization Activity. INORGANIC CHEMISTRY. 42:6592-6594.
  Full Text via DOI: 10.1021/ic0347236
- 2002
  
  Hydroformylation of 1-Hexene in Supercritical Carbon Dioxide Using a Heterogeneous Rhodium Catalyst. 2. Evaluation of Reaction Kinetics. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH. 41:4514-4522.
  Full Text via DOI: 10.1021/ie010791t
- 2002
  
  Hydroformylation of 1-hexene in supercritical carbon dioxide using a heterogeneous rhodium catalyst. 3. Evaluation of solvent effects. GREEN CHEMISTRY. 4:507-512.
  Full Text via DOI: 10.1039/b204822c
- 2001
  
  Acac-Promoted Rearrangement of an Alkylaluminophosphonate Tetramer to a Decamer. ORGANOMETALLICS. 20:4833-4839.
  Full Text via DOI: 10.1021/om010432y
- 2001
  
  Hindered Axial−Equatorial Carbonyl Exchange in an Fe(CO)4(PR3) Complex of a Rigid Bicyclic Phosphine. INORGANIC CHEMISTRY. 40:5001-5009.
  Full Text via DOI: 10.1021/ic001372b
- 2001
  
  Synthesis, Structure, and Coordination Chemistry of the Bicyclic π-Acid Phosphatri(3-methylindolyl)methane. ORGANOMETALLICS. 20:206-214.
  Full Text via DOI: 10.1021/om000793y
- 2000
  
  Alkylaluminophosphonate-catalyzed ring-opening homopolymerization of epichlorohydrin and propylene oxide. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 599:200-207.
  Full Text via DOI: 10.1016/s0022-328x(99)00764-0
- 2000
  
  Synthesis and Characterization of Chelating Triamide Complexes of Bismuth and Antimony. INORGANIC CHEMISTRY. 39:3931-3933.
  Full Text via DOI: 10.1021/ic991462k
- 1998
  
  Synthesis and Characterization of Dimeric, Trimeric, and Tetrameric Gallophosphonates and Gallophosphates⊥. INORGANIC CHEMISTRY. 37:3734-3746.
  Full Text via DOI: 10.1021/ic980132h
- 1997
  
  Cyclic and Cubic Organophosphonates of Gallium and Their Relationship to Structural Motifs in Gallophosphate Molecular Sieves. Angewandte Chemie International Edition in English. 36:239-241.
  Full Text via DOI: 10.1002/anie.199702391
- 1997
  
  Phenylarsonates of Aluminum and Gallium: Synthesis and Structural Characterization of [tBuAl(μ3-O3AsPh)]4 and [tBu2Ga(μ2-O2AsPh)]2O. INORGANIC CHEMISTRY. 36:6476-6478.
  Full Text via DOI: 10.1021/ic971168x
- 1996
  
  Organic-Soluble Cyclic and Cage Alkylaluminophosphates: X-ray Crystal Structure of [(tBu)2Al(μ2-O)2P(OSiMe3)2]2. INORGANIC CHEMISTRY. 35:5756-5757.
  Full Text via DOI: 10.1021/ic960619v
- 1995
  
  From minerals to materials: synthesis of alumoxanes from the reaction of boehmite with carboxylic acids. JOURNAL OF MATERIALS CHEMISTRY. 5:331-341.
  Full Text via DOI: 10.1039/jm9950500331
- 1994
  
  Tert-Butylaluminum Hydroxides and Oxides: Structural Relationship between Alkylalumoxanes and Alumina Gels. ORGANOMETALLICS. 13:2957-2969.
  Full Text via DOI: 10.1021/om00020a011
- 1993
  
  Hydrolysis of tri-tert-butylaluminum: the first structural characterization of alkylalumoxanes [(R2Al)2O]n and (RAlO)n. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 115:4971-4984.
  Full Text via DOI: 10.1021/ja00065a005
- 1993
  
  Sterically crowded aryloxide compounds of aluminium: hydrides and homoleptic aryloxides. Journal of the Chemical Society, Dalton Transactions. 441.
  Full Text via DOI: 10.1039/dt9930000441
- 1992
  
  Coordination chemistry of a new tetratertiary phosphine ligand. INORGANIC CHEMISTRY. 31:2746-2755.
  Full Text via DOI: 10.1021/ic00039a017
- 1992
  
  Fluoride-induced reduction of palladium(II) and platinum(II) phosphine complexes. ORGANOMETALLICS. 11:2212-2220.
  Full Text via DOI: 10.1021/om00042a040
- 1992
  
  Ligand substitution reactions in Group 6 metal carbonyl complexes of a novel bicyclic ditertiary phosphine ether. ORGANOMETALLICS. 11:1514-1520.
  Full Text via DOI: 10.1021/om00040a022
- 1991
  
  Bidentate and tridentate coordination modes of a novel bicyclic ditertiary phosphine ether. ORGANOMETALLICS. 10:2335-2344.
  Full Text via DOI: 10.1021/om00053a041
- 1987
  
  Metallo-ligands containing terminal oxygen donors bonded to a manganese–carbonyl moiety. Journal of the Chemical Society, Dalton Transactions. 2599-2603.
  Full Text via DOI: 10.1039/dt9870002599
Book Chapter (Web of Science)
- 2016
  
  Aluminum: Organometallic Chemistry. 1-26.
  Full Text via DOI: 10.1002/9781119951438.eibc0008.pub2
- 2015
  
  Aluminum-Based Catalysis. 1-22.
  Full Text via DOI: 10.1002/9781119951438.eibc2333
- 2006
  
  Aluminum: Organometallic ChemistryBased in part on the article Aluminum: Organometallic Chemistry by Gregory H. Robinson which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.
  Full Text via DOI: 10.1002/0470862106.ia008
- 2002
  
  Molecular Phosphates and Phosphonates of Aluminum and Gallium: Potential Applications in Materials Synthesis. ACS Symposium Series. 181-194.
  Full Text via DOI: 10.1021/bk-2002-0822.ch013
- 1994
  
  Reaction of Boehmite with Carboxylic Acids. ACS Symposium Series. 149-164.
  Full Text via DOI: 10.1021/bk-1994-0572.ch013
Chapter (Faculty180)
- 2021
  
  Greening the Curriculum at the University of Toledo School of Green Chemistry and Engineering. Green Chemistry and Technology. De Gruyter. 81-99.
- 2020
  
  Greening the Curriculum at the University of Toledo School of Green Chemistry and Engineering. Green Chemical Processes. Walter de Gruyter.
- 2016
  
  Aluminum: Organometallic Chemistry. Encyclopedia of Inorganic and Bioinorganic Chemistry, Scott, R. A., Editor. John Wiley.
- 2015
  
  Aluminum-Based Catalysis. The Lightest Metals: Science and Technology from Lithium to Calcium. John Wiley and Sons. 281-302.
Conference Poster (Faculty180)
Meeting Abstract (Web of Science)
- 2018
  
  One- pot synthesis of BODIPY- dyes through aerobic oxidation of bulky dipyrromethanes. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.
- 2012
  
  Conversion of bio-derived furfural to polymer precursors. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.
- 2012
  
  Synthesis, characterization, and reactivity of bulky dipyrromethene complexes of aluminum. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.
- 2008
  
  INOR 74-Bridging complexes of aluminum alkyls with di- and tri(3-methylindolyl)methanes. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.
- 2007
  
  INOR 1245-Reactivity of isocyanides with compounds of the Group 13 elements. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 209-209.
- 2007
  
  INOR 894-Di(3-methylindolyl)methane complexes of aluminum and gallium. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 253-253.
Note (Web of Science)
- 1991
  
  Unambiguous demonstration of vacant-site inversion in a cis-P2M(CO)3 intermediate. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 6309-6310.
  Full Text via DOI: 10.1021/ja00016a079
- 1990
  
  Fluoride-assisted reduction of palladium(II) phosphine complexes. ORGANOMETALLICS. 864-865.
  Full Text via DOI: 10.1021/om00117a053
Patent
- 2013
  
  Trianionic ligand precursor compounds and uses thereof in constrained geometry catalysts
Presentation (Faculty180)
Proceedings Paper (Web of Science)
- 1991
  
  From Minierals to Materlals: A Facile Synthetic Route to Preceraic Polymers for Aluminum Oxide. ADVANCED PRECISION ENGINEERING. 75.
  Full Text via DOI: 10.1557/proc-249-75

full name

Mark R Mason

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research areas

Chemistry