Joseph A. R. Schmidt
Contact Info
Publications
selected publications
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Article (Faculty180)
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2024Alpha-Metalated N,N-Dimethylbenzylamine Rare-Earth Metal Complexes and Their Catalytic Applications. Dalton Transactions. 53:13232-13247.
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2024Regiospecific Conversion of Aliphatic Allenes to Dithioacetals via Palladium-Catalyzed Double Hydrothiolation. European Journal of Inorganic Chemistry. in press.
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2022Heterodehydrocoupling of Silanes and Amines Catalyzed by a Simple Lanthanum-Based Complex. Organometallics. 41:2974-2984.
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2020Cationic Nickel(II) Catalyzed Hydrosilylation of Alkenes: Role of P,N-type Ligand Scaffold on Selectivity and Reactivity. Organometallics. 39:3441-3451.
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2020Double Hydrophosphorylation of Nitriles Mediated by Rare-Earth-Metal Lanthanum. The Journal of Organic Chemistry. 85:14720-14729.
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2020Nickel(II) catalyzed hydroboration: A route to selective reduction of aldehydes and N-allylimines. European Journal of Inorganic Chemistry. 1877–1884.
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2019Lanthanum-Catalyzed Regioselective Anti-Markovnikov Hydrophosphinylation of Styrenes. Organometallics. 38:4261-4270.
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2019Regioselective Single and Double Hydrophosphination and Hydrophosphinylation of Unactivated Alkynes. ACS Catalysis. 9:7143-7153.
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2017Lanthanum-Catalyzed Double Hydrophosphinylation of Nitriles. Organometallics. 36:721-729.
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2017Selective Hydrosilylation of Alkynes and Ketones: Contrasting Reactivity Between Cationic 3-Iminophosphine Palladium and Nickel Complexes. Dalton Transactions. 46:5431-5440.
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2016Cationic [(Iminophosphine)Nickel(Allyl)]+ Complexes as the First Example of Nickel Catalysts for Direct Hydroamination of Allenes. Chemistry -- A European Journal. 23:1507-1511.
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2016Selective Hydrosilylation of N-Allylimines Using a (3-Iminophosphine)palladium Precatalyst. Catalysis Science & Technology. 6:685-689.
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2015Electronic Role of 3-Iminophosphine Ligands in Palladium-Catalyzed Intermolecular Hydroamination. Organometallics. 34:1809-1817.
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2015
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2013
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2013
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2012Efficient Aryl Amination of Bromoarenes using a 3-Iminophosphine Palladium(II) Chloride Catalyst. Journal of Organometallic Chemistry. 720:7-18.
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2012
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2011Isolation and Characterization of Main Group and Late Transition Metal Complexes using orthoMetallated Imine Ligands. Dalton Transactions. 41:860-870.
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2011Synthesis and Reactivity of Homoleptic alpha-Metalated N,N-Dimethylbenzylamine Rare-Earth-Metal Complexes. Organometallics. 30:3915-3918.
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2010Derivatization of Niobium Complexes Bearing Imido and Acetophenone Imine Ligands. Organometallics. 29:6219-6229.
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2010Palladium(II) 3-Iminophosphine (3IP) Complexes: Active Precatalysts for the Intermolecular Hydroamination of 1,2-Dienes (Allenes) and 1,3-Dienes with Aliphatic Amines under Mild Conditions. Journal of Organometallic Chemistry. 696:179-187.
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2010Structural Characterization of Novel ortho-Lithiated Imines. European Journal of Inorganic Chemistry. 5146-5155.
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2009A Versatile Methodology for the Synthesis of alpha,beta-Unsaturated 3-Iminophosphines. Chemistry -- A European Journal. 15:2662-2673.
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2009Mono-Anionic Acetophenone Imine Ligands: Synthesis, Ortho-Lithiation, and First Examples of Group (V) Metal Complexes. Dalton Transactions. 4987-5000.
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2009Reactivity of (3-Iminophosphine)palladium(II) Complexes: Evidence of Hemilability. Organometallics. 28:2494-2504.
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2009Synthesis of Amine, Halide, and Pyridinium Terminated 2-Alkyl-p-tert-butylcalix[4]arenes. Tetrahedron. 65:8657-8667.
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2009
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2008Palladium(II) 3-Iminophosphine Complexes as Intermolecular Hydroamination Catalysts for the Formation of Imines and Enamines. Organometallics. 27:1259-1266.
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2007A Discrete Ortholithiated Acetophenone Imine Derivative: Isolation, Characterization, and Synthesis of Group IV Metal Complexes. Organometallics. 26:4094-4097.
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Article (Web of Science)
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2020Double Hydrophosphorylation of Nitriles Catalyzed by Rare-Earth-Metal Lanthanum. JOURNAL OF ORGANIC CHEMISTRY. 85:14720-14729.Full Text via DOI: 10.1021/acs.joc.0c02016 PMID: 33125235
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2020Cationic Nickel(II)-Catalyzed Hydrosilylation of Alkenes: Role of P, N-Type Ligand Scaffold on Selectivity and Reactivity. ORGANOMETALLICS. 39:3441-3451.Full Text via DOI: 10.1021/acs.organomet.0c00551
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2020Nickel(II) Catalyzed Hydroboration: A Route to Selective Reduction of Aldehydes and N-Allylimines. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2020:1877-1884.Full Text via DOI: 10.1002/ejic.202000092
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2019Lanthanum-Catalyzed Regioselective Anti-Markovnikov Hydrophosphinylation of Styrenes. ORGANOMETALLICS. 38:4261-4270.Full Text via DOI: 10.1021/acs.organomet.9b00549
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2019Regioselective Single and Double Hydrophosphination and Hydrophosphinylation of Unactivated Alkynes. ACS CATALYSIS. 9:7143-7153.Full Text via DOI: 10.1021/acscatal.9b01538
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2019Palladium-Based Hydroamination Catalysts Employing Sterically Demanding 3-Iminophosphines: Branched Kinetic Products by Prevention of Allylamine Isomerization. ORGANOMETALLICS. 38:1917-1927.Full Text via DOI: 10.1021/acs.organomet.9b00025
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2017Selective hydrosilylation of alkynes and ketones: contrasting reactivity between cationic 3-iminophosphine palladium and nickel complexes. DALTON TRANSACTIONS. 46:5431-5440.Full Text via DOI: 10.1039/c7dt00832e
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2017Lanthanum-Catalyzed Double Hydrophosphinylation of Nitriles. ORGANOMETALLICS. 36:721-729.Full Text via DOI: 10.1021/acs.organomet.6b00919
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2017Cationic [(Iminophosphine) Nickel( Allyl)](+) Complexes as the First Example of Nickel Catalysts for Direct Hydroamination of Allenes. CHEMISTRY-A EUROPEAN JOURNAL. 23:1507-1511.Full Text via DOI: 10.1002/chem.201605611
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2016Synthesis and extraction results of new halide terminated 2-alkyl-p-tert-butylcalix[4]arenes bearing phosphine oxides or ketones on the narrow rim. TETRAHEDRON. 72:767-774.Full Text via DOI: 10.1016/j.tet.2015.12.038
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2016Selective hydrosilylation of N-allylimines using a (3-iminophosphine)palladium precatalyst. CATALYSIS SCIENCE & TECHNOLOGY. 6:685-689.Full Text via DOI: 10.1039/c5cy01859e
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2015Electronic Role of 3-Iminophosphine Ligands in Palladium-Catalyzed Intermolecular Hydroamination. ORGANOMETALLICS. 34:1809-1817.Full Text via DOI: 10.1021/om500792k
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2015Highly efficient regioselective hydrosilylation of allenes using a [(3IP)Pd(allyl)]OTf catalyst; first example of allene hydrosilylation with phenyl- and diphenylsilane. CHEMICAL COMMUNICATIONS. 51:5943-5946.Full Text via DOI: 10.1039/c4cc09804h
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2013Easily assembled, modular N,O-chelating ligands for Ta(V) complexation: a comparative study of ligand effects in hydroaminoalkylation with N-methylaniline and 4-methoxy-N-methylaniline. TETRAHEDRON. 69:5737-5743.Full Text via DOI: 10.1016/j.tet.2013.04.070
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2013Insertion Reactions and Catalytic Hydrophosphination of Heterocumulenes using alpha-Metalated N,N-Dimethylbenzylamine Rare-Earth-Metal Complexes. ORGANOMETALLICS. 32:1141-1149.Full Text via DOI: 10.1021/om300807k
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2013Investigation of Steric and Electronic Features of 3-Iminophosphine-Based Palladium Catalysts for Intermolecular Hydroamination. ORGANOMETALLICS. 32:578-586.Full Text via DOI: 10.1021/om301102w
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2013Palladium catalyzed intermolecular hydroamination of 1-substituted allenes: an atom-economical method for the synthesis of N-allylamines. RSC ADVANCES. 3:20708-20718.Full Text via DOI: 10.1039/c3ra43870h
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2012Efficient catalytic aryl amination of bromoarenes using 3-iminophosphine palladium(II) chloride. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 720:7-18.Full Text via DOI: 10.1016/j.jorganchem.2012.08.027
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2012Hydroamination of 1,1-dimethylallene with primary aryl amines under mild conditions: An atom-economical route to N-(1,1-dimethyl-2-propenyl)-anilines. RSC ADVANCES. 2:128-131.Full Text via DOI: 10.1039/c1ra00795e
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2012Isolation and characterization of main group and late transition metal complexes using orthometallated imine ligands. DALTON TRANSACTIONS. 41:860-870.Full Text via DOI: 10.1039/c1dt11629k
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2011Synthesis and Reactivity of Homoleptic alpha-Metalated N,N-Dimethylbenzylamine Rare-Earth-Metal Complexes. ORGANOMETALLICS. 30:3915-3918.Full Text via DOI: 10.1021/om200363z
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2011Palladium(II) 3-iminophosphine (3IP) complexes: Active precatalysts for the intermolecular hydroamination of 1,2-dienes (allenes) and 1,3-dienes with aliphatic amines under mild conditions. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 696:179-187.Full Text via DOI: 10.1016/j.jorganchem.2010.08.033
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2010Derivatization of Niobium Complexes Bearing Imido and Acetophenone Imine Ligands. ORGANOMETALLICS. 29:6219-6229.Full Text via DOI: 10.1021/om100657r
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2010Structural Characterization of Novel ortho-Lithiated Imines. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 5146-5155.Full Text via DOI: 10.1002/ejic.201000516
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2009Synthesis of amine, halide, and pyridinium terminated 2-alkyl-p-tert-butylcalix[4]arenes. TETRAHEDRON. 65:8657-8667.Full Text via DOI: 10.1016/j.tet.2009.08.033
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2009Reactivity of (3-Iminophosphine)palladium(II) Complexes: Evidence of Hemilability. ORGANOMETALLICS. 28:2494-2504.Full Text via DOI: 10.1021/om900066t
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2009A Versatile Methodology for the Synthesis of alpha,beta-Unsaturated 3-Iminophosphines. CHEMISTRY-A EUROPEAN JOURNAL. 15:2662-2673.Full Text via DOI: 10.1002/chem.200802310
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2009Mono-anionic acetophenone imine ligands: synthesis, ortho-lithiation and first examples of group (V) metal complexes. DALTON TRANSACTIONS. 4987-5000.Full Text via DOI: 10.1039/b903836a
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2009Titanium imido complexes utilizing orthometallated derivatized acetophenone and piperonal imine ligands: synthesis, isolation, and characterization. DALTON TRANSACTIONS. 5001-5008.Full Text via DOI: 10.1039/b906461c
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2008Palladium(II) 3-iminophosphine complexes as intermolecular hydroamination catalysts for the formation of imines and enamines. ORGANOMETALLICS. 27:1259-1266.Full Text via DOI: 10.1021/om701106q
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2007A discrete ortho-lithiated acetophenone imine derivative: Isolation, characterization, and synthesis of group IV metal complexes. ORGANOMETALLICS. 26:4094-4097.Full Text via DOI: 10.1021/om700530z
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2005Chromium(III) Octaethylporphyrinato Tetracarbonylcobaltate: A Highly Active, Selective, and Versatile Catalyst for Epoxide Carbonylation. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 127:11426-11435.Full Text via DOI: 10.1021/ja051874u
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2005Synthesis and characterization of mono β-diketiminatosamarium amides and hydrocarbyls. DALTON TRANSACTIONS. 1387-1393.Full Text via DOI: 10.1039/b501437a
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2005Synthesis of an Epoxide Carbonylation Catalyst: Exploration of Contemporary Chemistry for Advanced Undergraduates. JOURNAL OF CHEMICAL EDUCATION. 82:621.Full Text via DOI: 10.1021/ed082p621
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2004A Readily Synthesized and Highly Active Epoxide Carbonylation Catalyst Based on a Chromium Porphyrin Framework: Expanding the Range of Available β-Lactones. ORGANIC LETTERS. 6:373-376.Full Text via DOI: 10.1021/ol036244g
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2003A cationic aluminum methyl complex supported by an anionic tacn ligand. INORGANICA CHIMICA ACTA. 351:404-408.Full Text via DOI: 10.1016/s0020-1693(03)00124-5
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2003Anionic triazacyclononanes: new supporting ligands in main group and transition metal organometallic chemistry. CHEMICAL COMMUNICATIONS. 1025-1033.Full Text via DOI: 10.1039/b208525a
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2002An unsolvated lithium trihydroaluminate and the correponding trialkynylaluminates supported by an anionic triazacyclononane ligand. Journal of the Chemical Society, Dalton Transactions. 2992-2994.Full Text via DOI: 10.1039/b202238a
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2002Divalent Lanthanide Metal Complexes of a Triazacyclononane-Functionalized Tetramethylcyclopentadienyl Ligand: X-ray Crystal Structures of [C5Me4SiMe2(iPr2-tacn)]LnI (Ln = Sm, Yb; tacn = 1,4-Diisopropyl-1,4,7-triazacyclononane). ORGANOMETALLICS. 21:3841-3844.Full Text via DOI: 10.1021/om020372b
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2002First-row transition metal complexes of sterically-hindered amidinates. Journal of the Chemical Society, Dalton Transactions. 3454-3461.Full Text via DOI: 10.1039/b202737m
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2002Neutral and Cationic Aluminum Complexes Supported by Sterically Bulky Amidinate Ligands. ORGANOMETALLICS. 21:2306-2313.Full Text via DOI: 10.1021/om0201011
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2002Reactions of N,N′,N″-trimethyl-1,4,7-triazacyclononane with butyllithium reagents. Journal of the Chemical Society, Dalton Transactions. 3273-3274.Full Text via DOI: 10.1039/b205792c
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2002Reactions of a Triazacyclononane-Supported Tantalum−Lithium Bridging Alkylidene with Organic Substrates. ORGANOMETALLICS. 21:3426-3433.Full Text via DOI: 10.1021/om020175c
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2002Synthesis and characterization of a series of sterically-hindered amidines and their lithium and magnesium complexes. Journal of the Chemical Society, Dalton Transactions. 2890-2899.Full Text via DOI: 10.1039/b202235b
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2001Alkyl and Alkylidene Tantalum−Lithium Complexes Supported by an Anionic Triazacyclononane Ligand. ORGANOMETALLICS. 20:1062-1064.Full Text via DOI: 10.1021/om0010621
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2001Reactivity of a Tantalum−Lithium Alkylidene Supported by an Anionic Triazacyclononane Ligand. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 123:8424-8425.Full Text via DOI: 10.1021/ja016143i
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2000Synthesis, Characterization, and Properties of a Lithium 21-Thiaporphyrin Complex. INORGANIC CHEMISTRY. 39:3424-3427.Full Text via DOI: 10.1021/ic000202w
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1999Mono-amidinate complexes stabilized by a new sterically-hindered amidine†. CHEMICAL COMMUNICATIONS. 2149-2150.Full Text via DOI: 10.1039/a905620c
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1996Gas-phase Reactions of Glycine, Alanine, Valineand theirN-Methyl Derivatives with theNitrosonium Ion, NO+. JOURNAL OF MASS SPECTROMETRY. 31:1086-1092.Full Text via DOI: 10.1002/(sici)1096-9888(199610)31:10<1086::aid-jms399>3.0.co;2-h
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1995Concerning the Regioselectivity of Gas Phase Reactions of Glycine with Electrophiles. The Cases of the Dimethylchlorinium Ion and the Methoxymethyl Cation. JOURNAL OF ORGANIC CHEMISTRY. 60:1990-1998.Full Text via DOI: 10.1021/jo00112a020
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1995Gas-phase methylation of the 2-hydroxypyridine/2-pyridone system by the dimethylchlorinium ion. European Journal of Mass Spectrometry. 1:457.Full Text via DOI: 10.1255/ejms.105
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Meeting Abstract (Web of Science)
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2015New calix[4]arene based precursors for stationary phases useful in separation of rare earth metals. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.
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2009Exploration of the chemistry of bidentate acetophenone imine ligands with Group V metals. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.
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2008INOR 669-Calixarene-based amine-terminated scorpionate ligands for lanthanides. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.
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2007INOR 304-Amine-containing calixarenes for lanthanide coordination. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.
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2007Design, synthesis, and reactivity of orthometallated acetophenone imine ligands and their niobium (V) complexes. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 904-904.
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2007Development of new group IV complexes employing bidentate orthometallated acetophenone imine ligands. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 911-911.
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2007Synthesis and reactivity of 3-iminophosphine palladium complexes. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 915-915.
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Review Article (Web of Science)
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2006Neutral and Cationic Alkyl Tantalum Imido Complexes: Synthesis and Migratory Insertion Reactions. ORGANOMETALLICS. 3394-3406.Full Text via DOI: 10.1021/om060081t
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Contact
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- Joseph A. R. Schmidt
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Cumulative publications in Scholars@UToledo